ZHANG Guangxu, FANG Yuan, CHEN Bo, GAO Weifang, ZHAO Xiaoshuang
. 2011, (11):
1-105.
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With cetyltrimethylammonium bromide as mouldboarding agent, tetraethyl orthosilicate as silica source, by adding metal salts solution directly into the process of synthesis which is the first step, we can get metal doped mesoporous molecular sieve MCM48 through hydrothermal synthesis in alkaline conditions. XRD, N2 adsorptiondesorption can characterize the structure of some product, and the results show that the metal doped mesoporous molecular sieve maintained the threedimensional cubic mesoporous structure, but the consistency was slightly lower and the specific surface decreased. Research on the hydrogen storage capability of this mesoporous molecular sieve suggests that the amount of hydrogen adsorption of pure MCM48 increases with temperature decreasing. At 0.2 MPa, -25 ℃, the amount of hydrogen adsorption can reach 0.678 8%; In metaldoped mesoporous molecular sieve, Ni, Fe, Pd can help improve the hydrogen storage capacity, Zr, Mg negatively will reduce the amount of hydrogen adsorption, of which NiMCM48 gets the highest amout of hydrogen adsorption at 0.2 MPa, -10 ℃, reaching 0.772 0%.