SI Peng, QIAO Xiuchen,YU Jianguo
. 2011, (5):
22-26.
Abstract (
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The influence of mechanochemical effect on Al(O,OH) polyhedron of kaolinite was investigated using Xray diffraction, infrared spectrum, magicanglespinning nuclear magnetic resonance, scanning electron microscope and hydrochloride acid leaching methods, compared with the thermal activation of kaolinite. The results showed that the Al(O,OH) octahedron of kaolinite was distorted gradually due to the mechanochemical effect, giving rise to an active substance with longrange disorder, in the simultaneous presence of 4, 5 and 6 coordinated Al. The AlVI in this substance was more abundant than that in metakaolinite, which was obtained through thermal activation. The mechanochemical effect also led to the dehydroxylation of Al(O,OH) octahedron of kaolinite, whereas part of the water involved in the structure of the active substance through coordination or hydrogen bond. The coordinated water was associated with Al, giving a new AlVI coordination of \[AlO5(H2O)\]. The activity of the AlVI in \[AlO5(H2O)\] was the same as the AlV in \[AlO5\], and higher than the AlVI of \[AlO6\] in metakaolinite.