High quality TiO2 nanomaterials were successively synthesized by liquid phase precipitation, using titanium pigment as raw material and NH4HCO3 as precipitator. The inference of calcination temperatures to phases, particle size and microstructure were studied. Research indicated that higher calcination temperature was, larger the particle size was. When calcination temperature was higher than 700 ℃, part of anatase changed into rutile; spherical TiO2 nanopowders with excellent microstructure performance and particle size about 10 nm was adopted when calcination temperature was 550 ℃.
姜锋，申镭诺，陈小波，肖晴，向周丹 .
Precipitation and Calcine Technology Research of TiO2 Materials. Journal of Wuhan University of Technology. 2011, 33(5): 18-21
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参考文献
〓周武艺, 唐绍裘, 张世英, 等．DBS包覆钛盐水解制备纳米TiO2的研究 . 硅酸盐学报, 2003,31(9): 859862. 〓Young B R, Won Y J, Man S L, et al. Hydrothermal Synthesis of Titanium Dioxides from Peroxotitanate Solution Using Basic Additive and Their Photocatalytic Activity on the Decomposition of Orange II . Journal of Physics and Chemistry of Solids, 2008, 69(5): 14571460. 〓Yu Jiaguo, Wang Guohong, Cheng Bei, et al. Effects of Hydrothermal Temperature and Time on the Photocatalytic Activity and Microstructures of Bimodal Mesoporous TiO2 Powders . Applied Catalysis B：Environmental ,2007,69(3):171180. 〓Shinichiro Kawasaki, Yan Xiuyi, Kiwamu Sue, et al. Continuous Supercritical Hydrothermal Synthesis of Controlled Size and Highly Crystalline Anatase TiO2 Nanoparticles . The Journal of Supercritical Fluids, 2009,50(3):276282. 〓Miki K, Sumpun W. Mixed Amorphous and Nanocrystalline TiO2 Powders Prepared by Solgel Method: Characterization and Photocatalytic Study . Materials Chemistry and Physics, 2008, 110(1):166175. 〓陈文梅, 赵修建. 溶胶凝胶法制备的TiO2薄膜结构对光催化活性的影响 . 功能材料,2001,32(1):8587. 〓Hyeok Choi, Yong Jin Kin, Rajender S Varma, et al. Thermally Stable Nanocrystalline TiO2 Photocatalysts Synthesized via Solgel Methods Modified with Ionic Liquid and Surfactant Molecules . Chemistry of Materials, 2006,18(22):53775384. 〓钱〓东, 闫早学, 石〓毛, 等. 溶胶凝胶法制备TiO2纳米颗粒及其光催化性能 . 中国有色金属学报,2005, 15(5):817822. 〓汪〓恂, 龚文琪．铁掺杂纳米TiO2膜的制备与光催化灭菌作用 . 武汉理工大学学报, 2007, 29(7):5053. Zhao De, Peng Tianyou, Xiao Jiangrong, et al. Preparation, Characterization and Photocatalytic Performance of Nd3+doped Titania Nanoparticles with Mesostructure . Materials Letters,2007,61(1):105110. 徐〓瑛, 张兆艳, 李志华, 等. 纳米TiO2的制备及其抗菌性能研究. 武汉理工大学学报, 2002, 24(7):13. 魏绍东, 王〓杏, 夏林胜. 沉淀法制备纳米TiO2的技术与工业生产 . 材料导报, 2005,19(z2): 113115. 曹爱红, 蓝心仁, 袁启明．沉淀法制备TiO2纳米粉体的研究 . 硅酸盐学报, 2002, 30(增刊): 8386. 刘仁龙．纳米TiO2光催化氧化处理苯酚水溶液的研究 . 重庆：重庆大学, 2004. Li W, Ni C, Lin H, et al. Size Dependence of Thermal Stability of TiO2 Nanoparticles . Journal of Applied Physics, 2004, 96(11): 66636668.
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